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Clay-polymer nanocomposites / edited by Khouloud Jlassi, Mohamed M. Chehimi, Sabu Thomas.

Contributor(s): Jlassi, Khouloud | Chehimi, Mohamed M | Thomas, SabuMaterial type: TextTextPublication details: Amsterdam : Elsevier, 2017Description: 1 online resourceContent type: text Media type: computer Carrier type: online resourceISBN: 9780323461610; 0323461611Subject(s): Composite materials | Nanostructured materials | Composite materials | Nanostructured materialsGenre/Form: Electronic books.Additional physical formats: Print version:: Clay-polymer nanocomposites.DDC classification: 620.1/18 LOC classification: TA418.9.C6Online resources: ScienceDirect
Contents:
Front Cover; Clay-Polymer Nanocomposites; Contents; List of Contributors; Biography; Preface; 1 -- Overview: Clay Preparation, Properties, Modification; 1. OVERVIEW ON CLAYS; 1.1 Introduction; 1.2 Crystal Structure and Classification of Clays; 1.2.1 The Phyllitic Clays; 1.2.2 The Fibrous Clays; 1.2.3 The Interlayered Clays; 1.3 Physicochemical Properties of Smectites; 1.3.1 Specific Surface Areas; 1.3.2 Cation Exchange Capacity; 1.3.3 Swelling of Smectites; 2. ORGANOMODIFICATION OF SMECTITE; 2.1 Modification by Cation Exchange.
2.1.1 Influence of the Hosting Structure and the Compensating Cation2.1.2 Influence of the Type of Alkyl Ammonium Ion; 2.1.3 Arrangement of Alkyl Ammonium Ions Between Sheets; 2.1.4 Use of Phosphonium Salts; 2.2 Adsorption of Polar Organic Molecules; 2.3 Grafting of Organosilanes; 2.4 Intercalation and Grafting of Diazonium Salts; 2.5 Alternative Intercalants; 2.6 Summary of Clay Modification Preprocessing for Formulation of Clay-Polymer Nanocomposites; 3. CONCLUSION; ACKNOWLEDGMENTS; REFERENCES; 2 -- An Overview of Polymer-Clay Nanocomposites; 1. INTRODUCTION.
1.1 Modification of Clay Particles1.2 Preparation Methods for Polymer-Clay Nanocomposites; 1.3 Possible Structures of Polymer-Clay Nanocomposites; 1.4 Classification of Clay Materials; 2. POLYMER/MODIFIED NATURAL CLAY-BASED NANOCOMPOSITES; 2.1 Smectite (2:1) Clay-Reinforced Polymer Nanocomposites; 2.1.1 Montmorillonite-Reinforced Polymer Nanocomposites; 2.1.2 Laponite-Reinforced Polymer Nanocomposites; 2.1.3 Sepiolite-Reinforced Polymer Nanocomposites; 2.1.4 Hectorite-Reinforced Polymer Nanocomposites; 2.1.5 Bentonite-Reinforced Polymer Nanocomposites.
2.2 Rectorite (1:1) Clay-Reinforced Polymer Nanocomposites2.3 Kaolinite Clay (1:1)-Reinforced Polymer Nanocomposites; 3. LAYERED DOUBLE HYDROXIDE-REINFORCED POLYMER NANOCOMPOSITES; 4. CONCLUSIONS; REFERENCES; 3 -- Multiscale Molecular Modeling of Clay-Polymer Nanocomposites; 1. INTRODUCTION; 2. MULTISCALE MOLECULAR MODELING; 3. MULTISCALE SIMULATIONS OF THERMOPLASTIC POLYURETHANE-BASED NANOCOMPOSITES; 3.1 Atomistic Simulations of Thermoplastic Polyurethane-Based Nanocomposites; 3.2 Mesoscopic Simulations of Thermoplastic Polyurethane-Based Nanocomposites.
3.3 Finite Element Simulations of Thermoplastic Polyurethane-Based Nanocomposites4. RESULTS FROM MULTISCALE SIMULATIONS OF THERMOPLASTIC POLYURETHANE-BASED NANOCOMPOSITES; 5. CONCLUDING REMARKS; ACKNOWLEDGMENTS; REFERENCES; 4 -- Clay-Polymer Composites: Design of Clay Polymer Nanocomposite by Mixing; 1. MIXING; 2. MIXING EQUIPMENT; 3. CLAY-POLYMER NANOCOMPOSITES VIA MELT MIXING; 4. CLAY-POLYMER NANOCOMPOSITES VIA SOLUTION MIXING; 5. OVERVIEW OF MORPHOLOGY OF CLAY-POLYMER NANOCOMPOSITES; 5.1 Clay Morphology in Rubber Matrix; 5.2 Clay Morphology in Thermoplastic Matrix.
Summary: Annotation 'Clay-Polymer Nanocomposites' is a complete summary of the existing knowledge on this topic, from the basic concepts of synthesis and design to their applications in timely topics such as high-performance composites, environment, and energy issues. This textovers many aspects of synthesis such as in- situ polymerization within the interlamellar spacing of the clays or by reaction of pristine or pre-modified clays with reactive polymers and prepolymers.
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Front Cover; Clay-Polymer Nanocomposites; Contents; List of Contributors; Biography; Preface; 1 -- Overview: Clay Preparation, Properties, Modification; 1. OVERVIEW ON CLAYS; 1.1 Introduction; 1.2 Crystal Structure and Classification of Clays; 1.2.1 The Phyllitic Clays; 1.2.2 The Fibrous Clays; 1.2.3 The Interlayered Clays; 1.3 Physicochemical Properties of Smectites; 1.3.1 Specific Surface Areas; 1.3.2 Cation Exchange Capacity; 1.3.3 Swelling of Smectites; 2. ORGANOMODIFICATION OF SMECTITE; 2.1 Modification by Cation Exchange.

2.1.1 Influence of the Hosting Structure and the Compensating Cation2.1.2 Influence of the Type of Alkyl Ammonium Ion; 2.1.3 Arrangement of Alkyl Ammonium Ions Between Sheets; 2.1.4 Use of Phosphonium Salts; 2.2 Adsorption of Polar Organic Molecules; 2.3 Grafting of Organosilanes; 2.4 Intercalation and Grafting of Diazonium Salts; 2.5 Alternative Intercalants; 2.6 Summary of Clay Modification Preprocessing for Formulation of Clay-Polymer Nanocomposites; 3. CONCLUSION; ACKNOWLEDGMENTS; REFERENCES; 2 -- An Overview of Polymer-Clay Nanocomposites; 1. INTRODUCTION.

1.1 Modification of Clay Particles1.2 Preparation Methods for Polymer-Clay Nanocomposites; 1.3 Possible Structures of Polymer-Clay Nanocomposites; 1.4 Classification of Clay Materials; 2. POLYMER/MODIFIED NATURAL CLAY-BASED NANOCOMPOSITES; 2.1 Smectite (2:1) Clay-Reinforced Polymer Nanocomposites; 2.1.1 Montmorillonite-Reinforced Polymer Nanocomposites; 2.1.2 Laponite-Reinforced Polymer Nanocomposites; 2.1.3 Sepiolite-Reinforced Polymer Nanocomposites; 2.1.4 Hectorite-Reinforced Polymer Nanocomposites; 2.1.5 Bentonite-Reinforced Polymer Nanocomposites.

2.2 Rectorite (1:1) Clay-Reinforced Polymer Nanocomposites2.3 Kaolinite Clay (1:1)-Reinforced Polymer Nanocomposites; 3. LAYERED DOUBLE HYDROXIDE-REINFORCED POLYMER NANOCOMPOSITES; 4. CONCLUSIONS; REFERENCES; 3 -- Multiscale Molecular Modeling of Clay-Polymer Nanocomposites; 1. INTRODUCTION; 2. MULTISCALE MOLECULAR MODELING; 3. MULTISCALE SIMULATIONS OF THERMOPLASTIC POLYURETHANE-BASED NANOCOMPOSITES; 3.1 Atomistic Simulations of Thermoplastic Polyurethane-Based Nanocomposites; 3.2 Mesoscopic Simulations of Thermoplastic Polyurethane-Based Nanocomposites.

3.3 Finite Element Simulations of Thermoplastic Polyurethane-Based Nanocomposites4. RESULTS FROM MULTISCALE SIMULATIONS OF THERMOPLASTIC POLYURETHANE-BASED NANOCOMPOSITES; 5. CONCLUDING REMARKS; ACKNOWLEDGMENTS; REFERENCES; 4 -- Clay-Polymer Composites: Design of Clay Polymer Nanocomposite by Mixing; 1. MIXING; 2. MIXING EQUIPMENT; 3. CLAY-POLYMER NANOCOMPOSITES VIA MELT MIXING; 4. CLAY-POLYMER NANOCOMPOSITES VIA SOLUTION MIXING; 5. OVERVIEW OF MORPHOLOGY OF CLAY-POLYMER NANOCOMPOSITES; 5.1 Clay Morphology in Rubber Matrix; 5.2 Clay Morphology in Thermoplastic Matrix.

Includes index.

Print version record.

Includes bibliographical references and index.

Annotation 'Clay-Polymer Nanocomposites' is a complete summary of the existing knowledge on this topic, from the basic concepts of synthesis and design to their applications in timely topics such as high-performance composites, environment, and energy issues. This textovers many aspects of synthesis such as in- situ polymerization within the interlamellar spacing of the clays or by reaction of pristine or pre-modified clays with reactive polymers and prepolymers.

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